CEE 680 |
18 October 1996 |
|---|
FIRST EXAM
Closed book, one page of notes allowed.
Answer all questions. Please state any additional assumptions you made, and show all work.
Miscellaneous Information:
R = 1.987 cal/mole°K = 8.314 J/mole°K
Absolute zero = -273.15°C
1 joule = 0.239 calories
1015 newtons = 1 figanewton
Selected Acidity Constants (Aqueous Solution, 25°C, I = 0)
NAME |
FORMULA |
pKa |
|---|---|---|
Perchloric acid |
HClO4 = H+ + ClO4- |
-7 STRONG |
Hydrochloric acid |
HCl = H+ + Cl- |
-3 |
Sulfuric acid |
H2SO4= H+ + HSO4- |
-3 (&2) ACIDS |
Nitric acid |
HNO3 = H+ + NO3- |
-0 |
Hydronium ion |
H3O+ = H+ + H2O |
0 |
Trichloroacetic acid |
CCl3COOH = H+ + CCl3COO- |
0.70 |
Iodic acid |
HIO3 = H+ + IO3- |
0.8 |
Bisulfate ion |
HSO4- = H+ + SO4-2 |
2 |
Phosphoric acid |
H3PO4 = H+ + H2PO4- |
2.15 (&7.2,12.3) |
o-Phthalic acid |
C6H4(COOH)2 = H+ + C6H4(COOH)COO- |
2.89 (&5.51) |
Citric acid |
C3H5O(COOH)3= H+ + C3H5O(COOH)2COO- |
3.14 (&4.77,6.4) |
Hydrofluoric acid |
HF = H+ + F- |
3.2 |
Aspartic acid |
C2H6N(COOH)2= H+ + C2H6N(COOH)COO- |
3.86 (&9.82) |
m-Hydroxybenzoic acid |
C6H4(OH)COOH = H+ + C6H4(OH)COO- |
4.06 (&9.92) |
p-Hydroxybenzoic acid |
C6H4(OH)COOH = H+ + C6H4(OH)COO- |
4.48 (&9.32) |
Nitrous acid |
HNO2 = H+ + NO2- |
4.5 |
Acetic acid |
CH3COOH = H+ + CH3COO- |
4.75 |
Propionic acid |
C2H5COOH = H+ + C2H5COO- |
4.87 |
Carbonic acid |
H2CO3 = H+ + HCO3- |
6.35 (&10.33) |
Hydrogen sulfide |
H2S = H+ + HS- |
7.02 (&13.9) |
Dihydrogen phosphate |
H2PO4- = H+ + HPO4-2 |
7.2 |
Hypochlorous acid |
HOCl = H+ + OCl- |
7.5 |
Boric acid |
B(OH)3 + H2O = H+ + B(OH)4- |
9.2 (&12.7,13.8) |
Ammonium ion |
NH4+ = H+ + NH3 |
9.24 |
Hydrocyanic acid |
HCN = H+ + CN- |
9.3 |
p-Hydroxybenzoic acid |
C6H4(OH)COO- = H+ + C6H4(O)COO-2 |
9.32 |
Phenol |
C6H5OH = H+ + C6H5O- |
9.9 |
m-Hydroxybenzoic acid |
C6H4(OH)COO- = H+ + C6H4(O)COO-2 |
9.92 |
Bicarbonate ion |
HCO3- = H+ + CO3-2 |
10.33 |
Monohydrogen phosphate |
HPO4-2 = H+ + PO4-3 |
12.3 |
Bisulfide ion |
HS- = H+ + S-2 |
13.9 |
Water |
H2O = H+ + OH- |
14.00 |
Ammonia |
NH3 = H+ + NH2- |
23 |
Methane |
CH4 = H+ + CH3- |
34 |
Thermodynamic Properties at Standard Temperature & Pressure@
Species |
Gibbs Free Energy of Formation (kJ/mol) |
Enthalpy of Formation (kJ/mol) |
Entropy of Formation (kJ/ mol) |
|---|---|---|---|
H2CO3* (aq) |
-623.2 |
-699.6 |
187.0 |
CO2 (g) |
-394.37 |
-393.5 |
213.6 |
HCO3- (aq) |
-586.8 |
-692.0 |
91.2 |
CO3-2 (aq) |
-527.9 |
-677.1 |
-56.9 |
H+ (aq) |
0 |
0 |
0 |
H2O (l) |
-237.18 |
-285.83 |
69.91 |
H2O (g) |
-228.57 |
-241.8 |
188.72 |
OH- (aq) |
-157.29 |
-230.0 |
-10.75 |
@From Stumm & Morgan, 1996